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Nitrites only date back to the middle of the 19th century.
We've been smoking, salting, and otherwise preserving meat for way longer than that, though. People usually died off from other things before cancer got them, that's all. The relatively high number of cancer deaths is a product of medical intervention getting so good and so widespread that we don't regularly die of sepsis from stepping on a splinter or catching communicable disease anymore.
Absolutely, fuck cancer. But cancer went from being a minor concern to a relatively common one because we conquered so many other avenues of death, systematically and carefully, until we're down to time, neglect and negligence as the three main ways humanity gets itself to the Reaper.
Isolated as a pure salt, maybe. All those "uncured" varieties listing celery as an ingredient are making use of the same compound though.